NMR studies of pi molecular complexes in iron porphyrins

LAUR Repository

Show simple item record

dc.contributor.author Kabbani, Ahmad T.
dc.date.accessioned 2018-08-13T09:23:55Z
dc.date.available 2018-08-13T09:23:55Z
dc.date.copyright 1979 en_US
dc.date.issued 2018-08-13
dc.identifier.uri http://hdl.handle.net/10725/8313
dc.description.abstract Proton and carbon-13 NMR shifts and linewidths of a series of synthetic high-spin ferric porphyrin were investigated upon the addition of various aromatic pi acceptors and donors. The interactions are described by the formation of 1:1 adducts. Thermodynamics of the complex chloro(Tetraphenylporphyrin)-iron (3)/1,3,5-trinitrobenzene are indicative of pi-pi peripheral contact of the aromatic substrate with the porphyrin. Successful use of NMR was made to demonstrate the utility of intramolecular dipolar relaxation, induced at proton and carbon-13 of trinitrobenzene resonance by the ferric ion, in the determination of the solution structure of the pi molecular complex chloro(tetraphenylporphyrin) iron(3)/1,3,5-trinitrobenzene. en_US
dc.language.iso en en_US
dc.title NMR studies of pi molecular complexes in iron porphyrins en_US
dc.type Thesis en_US
dc.author.degree PHD en_US
dc.author.school SAS en_US
dc.author.idnumber 198029470 en_US
dc.author.department Natural Sciences en_US
dc.description.embargo N/A en_US
dc.keywords Iron Compound en_US
dc.keywords Nuclear magnetic resonance en_US
dc.keywords Porphyrins en_US
dc.keywords Atomic structure en_US
dc.keywords Carbon 13 en_US
dc.keywords Line spectra en_US
dc.keywords Molecular relaxation en_US
dc.keywords Nitrobenzenes en_US
dc.keywords Protons en_US
dc.keywords Shift en_US
dc.keywords Thermodynamics en_US
dc.keywords Trinitro compounds en_US
dc.keywords Molecular structure en_US
dc.description.bibliographiccitations Includes bibliographical references en_US
dc.identifier.ctation Kabbani, A. T. (1979). NMR studies of pi molecular complexes in iron porphyrins. en_US
dc.author.email akabbani@lau.edu.lb en_US
dc.identifier.tou http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php en_US
dc.identifier.url http://adsabs.harvard.edu/abs/1979PhDT........17K en_US
dc.publisher.institution California University en_US
dc.author.affiliation Lebanese American University en_US

Files in this item

Files Size Format View

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record

Search LAUR

Advanced Search


My Account