Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis

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dc.contributor.author Khnayzer, Rony S.
dc.contributor.author McCusker, Catherine E.
dc.contributor.author Olaiya, Babatunde S.
dc.contributor.author Castellano, Felix N.
dc.date.accessioned 2017-11-03T07:13:24Z
dc.date.available 2017-11-03T07:13:24Z
dc.date.copyright 2013 en_US
dc.date.issued 2017-11-03
dc.identifier.issn 0002-7863 en_US
dc.identifier.uri http://hdl.handle.net/10725/6489
dc.description.abstract The Cu(I) metal-to-ligand charge-transfer complex, [Cu(dsbtmp)2]+ (dsbtmp = 2,9-di(sec-butyl)-3,4,7,8-tetramethyl-1,10-phenanthroline), exhibits outstanding stability as a visible-light-absorbing photosensitizer in hydrogen-evolving homogeneous photocatalysis. In concert with the Co(dmgH)2(py)Cl water reduction catalyst and N,N-dimethyl-p-toluidine sacrificial donor in 1:1 H2O:CH3CN, this Cu(I) sensitizer remains active even after 5 days of visible-light-pumped (λex = 452 ± 10 nm) hydrogen evolution catalysis. Deuteration studies illustrate that the hydrogen produced from this composition does indeed originate from aqueous protons. en_US
dc.language.iso en en_US
dc.title Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis en_US
dc.type Article en_US
dc.description.version Published en_US
dc.author.school SAS en_US
dc.author.idnumber 200501196 en_US
dc.author.department Natural Sciences en_US
dc.description.embargo N/A en_US
dc.relation.journal Journal of the American Chemical Society en_US
dc.journal.volume 135 en_US
dc.journal.issue 38 en_US
dc.article.pages 14068-14070 en_US
dc.identifier.doi http://dx.doi.org/10.1021/ja407816f en_US
dc.identifier.ctation Khnayzer, R. S., McCusker, C. E., Olaiya, B. S., & Castellano, F. N. (2013). Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis. Journal of the American Chemical Society, 135(38), 14068-14070. en_US
dc.author.email rony.khnayzer@lau.edu.lb en_US
dc.identifier.tou http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php en_US
dc.identifier.url http://pubs.acs.org/doi/abs/10.1021/ja407816f en_US
dc.orcid.id https://orcid.org/0000-0001-7775-0027 en_US
dc.author.affiliation Lebanese American University en_US

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