Pre-Chemiluminescent biexponential degradation of bis(2,4-dinitrophenyl) oxalate in hydrogen peroxide-acetonitrile

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dc.contributor.author Capomacchia, Anthony C.
dc.contributor.author Jennings, R.N.
dc.date.accessioned 2017-10-18T08:26:28Z
dc.date.available 2017-10-18T08:26:28Z
dc.date.copyright 1989 en_US
dc.date.issued 2017-10-18
dc.identifier.issn 1873-4324 en_US
dc.identifier.uri http://hdl.handle.net/10725/6346
dc.description.abstract The pre-chemiluminescent hydrogen peroxide-bis(2,4-dinitrophenyl) oxalate reaction has been studied in order to understand better its role in peroxyoxalate chemiluminescence. The reaction is shown to be first order in each reactant. An unusual biexponential degradation of the oxalate occurs which suggests that it exists in solution as two conformations that react with hydrogen peroxide at different rates. Inclusion of the fluorophor 9,10-diphenylanthracene does not affect the reaction rate. en_US
dc.language.iso en en_US
dc.title Pre-Chemiluminescent biexponential degradation of bis(2,4-dinitrophenyl) oxalate in hydrogen peroxide-acetonitrile en_US
dc.type Article en_US
dc.description.version Published en_US
dc.author.school SOP en_US
dc.author.idnumber 201408778 en_US
dc.author.department Pharmaceutical Sciences Department en_US
dc.description.embargo N/A en_US
dc.relation.journal Analytica Chimica Acta en_US
dc.journal.volume 227 en_US
dc.journal.issue 37-48 en_US
dc.article.pages 37-48
dc.identifier.doi https://doi.org/10.1016/S0003-2670(00)82643-4 en_US
dc.identifier.ctation Jennings, R. N., & Capomacchia, A. C. (1989). Pre-Chemiluminescent biexponential degradation of bis (2, 4-dinitrophenyl) oxalate in hydrogen peroxide-acetonitrile. Analytica chimica acta, 227, 37-48. en_US
dc.author.email anthony.capomacchia@lau.edu.lb en_US
dc.identifier.tou http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php en_US
dc.identifier.url http://www.sciencedirect.com/science/article/pii/S0003267000826434 en_US
dc.author.affiliation Lebanese American University en_US

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